Ye Sun, Yuan Meng, Xiaoyan Guo書頻, Tianle Zhu, et al.Study of nitr什機ogen oxide absorption in th匠匠e calcium sulfite slurry
發布日期:2020-04-21浏覽次數:
次信息來源: JSMCWM
Abstract: Experiments were conducte匠鐘d using a bubbling reactor 理服to investigate nitro民歌gen oxide absorption i窗鐘n the calcium sulfite sl是窗urry. The effects of CaSO3 concentration, NO2/NO mole ratio and O2 concentrations on NO2 and SO2 absorption efficiencies were i一制nvestigated. Five types of additives, 有哥including MgSO4, Na2SO4, FeSO4, MgSO4/Na2SO4 and FeSO4/Na2SO4, had been evaluated for enha金火ncing NO2 absorption in CaSO3 slurry. Results showed that CaSO3 concentration had significant imp筆冷act on NO2 and SO2 absorption efficiencies, and the highe船知st absorption efficiencies of SO2 and NO2 could reach about 99.5 and 75.0 %, r票姐espectively. Furthermor都樹e, the NO2 absorption was closely related t的風o the NO2/NO mole ratio, and the exis月湖tence of NO2 in flue gas may promote NO absor就照ption. The presence of O2 in simulated flue gas wa唱如s disadvantage for NO(x) rem們少oval because it can oxidiz議算e sulfite to sulfate.放東 It was worth pointing out that FeS紙照O4/Na2SO4 was the best additive among those inv吧朋estigated additives, as the NO兒線2 removal efficiency was sig事河nificantly increased from 74.8 to 9你員5.0 %. IC and in situ FTIR r下朋esults suggest that the main products 亮票were NO3- and NO2- in liquid phase and N2O, N2O5 and HNO3 in gas phase during the CaSO3 absorption process.