Ye Sun, Yuan Meng, Xiao光國yan Guo, Tianle Zhu, 劇秒et al.Study of nitro遠視gen oxide absorption in t男暗he calcium sulfite slurry

發布日期:2020-04-21浏覽次數: 信息來源: JSMCWM

      Abstract: Experiments were conducted us章女ing a bubbling reactor to 中書investigate nitrogen綠能 oxide absorption in th明科e calcium sulfite slurry. The effects飛票 of CaSO3 concentration, NO2/NO mole ratio and O從湖2 concentrations on NO2 and SO2 absorption efficiencies were investigat公器ed. Five types of additives,行月 including MgSO4, Na2SO4, FeSO4, MgSO4/Na2SO4 and FeSO4/Na2SO4, had been evaluated for enha他光ncing NO2 absorption in CaSO3 slurry. Results showed t自購hat CaSO3 concentration had signific慢女ant impact on NO2 and SO2 absorption efficienci物商es, and the highest absorption efficien也內cies of SO2 and NO2 could reach about 99.5 and 75.0 %, 女就respectively. Furthe農科rmore, the NO2 absorption was closely related to th吃報e NO2/NO mole ratio, and the existenc笑嗎e of NO2 in flue gas may promot雪雜e NO absorption. The prese工劇nce of O2 in simulated flue gas視科 was disadvantage for NO報土(x) removal because 討問it can oxidize sulfite to 如很sulfate. It was worth pointing out th村是at FeSO4/Na2SO4 was the best additive among those i光快nvestigated additives, as 討知the NO2 removal efficiency was signif間坐icantly increased from 74.8 to 95.0報媽 %. IC and in situ FTIR results sug術科gest that the main products were NO3- and NO2- in liquid phase and N2O, N2O5 and HNO3 in gas phase during the CaSO話工3 absorption process.