Ye Sun, Yuan Meng, Xiaoyan事國 Guo, Tianle Zhu, et al.Study of nitr唱吃ogen oxide absorption in 銀相the calcium sulfite 照火slurry

發布日期:2020-04-21浏覽次數: 信息來源: JSMCWM

      Abstract: Experiments were conducted using 雪用a bubbling reactor to investigate ni知照trogen oxide absorption in the綠嗎 calcium sulfite slurry. The購信 effects of CaSO3 concentration, NO2/NO mole ratio and O2 concentrations on NO2 and SO2 absorption efficiencies were investigat妹家ed. Five types of additives,為信 including MgSO4, Na2SO4, FeSO4, MgSO4/Na2SO4 and FeSO4/Na2SO4, had been evaluated for enhancing N志會O2 absorption in CaSO3 slurry. Results showed that CaSO3 concentration had significant i行藍mpact on NO2 and SO2 absorption efficiencies, and t那紅he highest absorption effic光美iencies of SO2 and NO2 could reach about 99.5 and 75國愛.0 %, respectively. Furthe雨短rmore, the NO2 absorption was closely rel草腦ated to the NO2/NO mole ratio, and the ex習雜istence of NO2 in flue gas may promote NO用照 absorption. The pre短師sence of O2 in simulated flue gas 生影was disadvantage for NO(x)拍內 removal because it ca事間n oxidize sulfite to sulfate. It was wo筆東rth pointing out that FeSO4/Na2SO4 was the best additive among those inv醫得estigated additives, as the也技 NO2 removal efficiency was significantly 我問increased from 74.8 to 95.0 村劇%. IC and in situ FTIR煙紅 results suggest that the 微子main products were NO3- and NO2- in liquid phase and N2O, N2O5 and HNO3 in gas phase during the CaSO3 absorption process.